The Argentine veteran scored in his customary manner and thoroughly outclassed the opposition to help PSG secure a decisive victory over Maccabi Haifa.
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PSG defeated CSKA Moscow 7-2 in the game that was played on Tuesday.
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Messi broke yet another incredible record as PSG prevailed.
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Messi opened the scoring in Tuesday's game in the 19th minute, and he quickly added another goal shortly before the break.
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With the second goal, Messi cemented his place in history and rose to the top of the list of Champions League goal scorers.
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Together, Lionel Messi and Cristiano Ronaldo scored 22 goals while holding this position.
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Messi set a new mark by scoring the game's second goal, his 23rd overall.
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Only Messi has appeared in the top 5 European leagues.
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The PSG striker became the first player to score in a UEFA competition against 29 different opponents.
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Ronaldo, who plays for Manchester United, has one fewer goal than Messi overall over 28 clubs.